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It is possible that this shoulder is partly due to the K-beta emission of the material used in this particular experiment which happens to be copper (while the main peak is the K-alpha emission). After a quick loop-up, these values for copper are approximately 8040 keV for K-alpha and 8900 keV for K-beta which gives a 1.107 ratio of K-beta to K-alpha. If we look at the distribution of just the maximum energy pixel of each peak, as shown below, there is very visibly some type of peak on the higher energy side of the 1 pixel distribution. The main peak has a mean of 140.3 while the mean of the smaller peak is about 155. This gives a ratio of 1.104. The numbers used are approximations and the second peak is artificially shifted by the Gaussian from the first peak underlying it. So it is very likely that these two peaks are the K-alpha and K-beta lines of copper.

V1 vs. V4

Closer Look at the Effect of Pixel Size

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